A metal, M forms chlorides in its and oxidation states. Which of the following statements about these chlorides is correct?
- Ais more volatile than
- Bis more soluble in anhydrous ethanol than
- Cis more ionic than
- Dis more easily hydrolysed than
Solution & Step-by-step Explanation
According to Fajans' Rules, for a given anion, a higher positive charge on the cation leads to greater polarization of the anion, resulting in more covalent character. has a higher charge and smaller size than .Therefore, is more covalent and is more ionic.Covalent compounds () are generally more volatile and more soluble in organic solvents like ethanol.Higher oxidation state halides are also more easily hydrolysed.