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A metal, M forms chlorides in its and oxidation states. Which of the following statements about these chlorides is correct?

  1. A
    is more volatile than
  2. B
    is more soluble in anhydrous ethanol than
  3. C
    is more ionic than
  4. D
    is more easily hydrolysed than

Solution & Step-by-step Explanation

According to Fajans' Rules, for a given anion, a higher positive charge on the cation leads to greater polarization of the anion, resulting in more covalent character. has a higher charge and smaller size than .Therefore, is more covalent and is more ionic.Covalent compounds () are generally more volatile and more soluble in organic solvents like ethanol.Higher oxidation state halides are also more easily hydrolysed.

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A metal, M forms chlorides in its and oxidation states. Which of the following statements about these chlorides is correct?
A
is more volatile than
B
is more soluble in anhydrous ethanol than
C
is more ionic than
D
is more easily hydrolysed than

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