Amount of oxalic acid present in a solution can be determined by its titration with solution in the presence of . The titration gives unsatisfactory results when carried out in the presence of because :
- Agets oxidized by oxalic acid to chlorine
- Bfurnishes ions in addition to those from oxalic acid
- Creduces permanganate to
- Doxidizes oxalic acid to carbon dioxide and water
Solution & Step-by-step Explanation
is a strong oxidizing agent. In the presence of , can oxidize ions to gas. This competes with the oxidation of oxalic acid, leading to incorrect consumption of and unsatisfactory titration results.