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Assertion : Alkyl isocyanides in acidified water give alkyl formamides.Reason : In isocyanides, carbon first acts as a nucleophile and then as an electrophile.

  1. A
    (a)
  2. B
    (b)
  3. C
    (c)
  4. D
    (d)

Solution & Step-by-step Explanation

Alkyl isocyanides () undergo partial hydrolysis in acidified water to form -alkylformamides (). In the mechanism, the terminal carbon of the isocyanide group initially acts as a nucleophile to pick up a proton () or react with an electrophile, and subsequently becomes an electrophilic center that is attacked by a nucleophile like water. Both assertion and reason are true, and the reason correctly explains the chemical reactivity leading to the product.

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Assertion : Alkyl isocyanides in acidified water give alkyl formamides.Reason : In isocyanides, carbon first acts as a nucleophile and then as an electrophile.
A
(a)
B
(b)
C
(c)
D
(d)

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