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At , the vapour pressure of pure liquid ‘A’ is and that of pure liquid ‘B’ is . If a mixture solution of ‘A’ and ‘B’ boils at and pressure, the amount of ‘A’ in the mixture is ():

  1. A
  2. B
  3. C
  4. D

Solution & Step-by-step Explanation

A liquid boils when its total vapour pressure equals the external atmospheric pressure ().According to Raoult's Law:

Since :




Thus, the mole percent of A is .

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At , the vapour pressure of pure liquid ‘A’ is and that of pure liquid ‘B’ is . If a mixture solution of ‘A’ and ‘B’ boils at and pressure, the amount of ‘A’ in the mixture is ():
A
B
C
D

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