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Iron exhibits and oxidation states. Which of the following statements about iron is incorrect?

  1. A
    Ferrous oxide is more basic in nature than the ferric oxide.
  2. B
    Ferrous compounds are relatively more ionic than the corresponding ferric compounds
  3. C
    Ferrous compounds are less volatile than the corresponding ferric compounds.
  4. D
    Ferrous compounds are more easily hydrolysed than the corresponding ferric compounds.

Solution & Step-by-step Explanation

In Ferric () compounds, the charge is higher and the size of the ion is smaller compared to Ferrous (). According to Fajan's rules, the ion has a higher polarizing power, leading to more covalent character and easier hydrolysis. Therefore, Ferric compounds are more easily hydrolysed, making option D incorrect.

Practice this question

Try it yourself before checking the explanation above.

Iron exhibits and oxidation states. Which of the following statements about iron is incorrect?
A
Ferrous oxide is more basic in nature than the ferric oxide.
B
Ferrous compounds are relatively more ionic than the corresponding ferric compounds
C
Ferrous compounds are less volatile than the corresponding ferric compounds.
D
Ferrous compounds are more easily hydrolysed than the corresponding ferric compounds.

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