Nitration of aniline in strong acidic medium also gives m-nitroaniline because:
- AIn absence of substituents nitro group always goes to m-position
- BIn electrophilic substitution reactions amino group is meta directive
- CInspite of substituents nitro group always goes to only m-position
- DIn acidic (strong) medium aniline is present as anilinium ion
Solution & Step-by-step Explanation
Aniline is highly reactive and its group is -directing. However, nitration is carried out in a mixture of conc. and . In this strongly acidic medium, aniline gets protonated to form the anilinium ion (). The anilinium ion is a strong electron-withdrawing group and is meta-directing. This results in a significant amount (approx. ) of -nitroaniline being formed.