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Phosphoric acid ionizes in three steps with their ionization constant values , and , respectively, while is the overall ionization constant. Which of the following statements are true?A. B. is a stronger acid than and C. D. Choose the correct answer from the options given below:

  1. A
    A and B only
  2. B
    A and C only
  3. C
    B, C and D only
  4. D
    A, B and C only

Solution & Step-by-step Explanation

1. For a polyprotic acid, the overall equilibrium constant . Taking logs: . Statement A is true.2. Acid strength decreases as protons are removed because it is harder to remove a positive proton from a more negatively charged ion. Thus, . Statement B is true.3. Successive ionization constants always decrease: . Statement C is true.4. Statement D is incorrect as the constants differ by several orders of magnitude.Statements A, B, and C are true.

Practice this question

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Phosphoric acid ionizes in three steps with their ionization constant values , and , respectively, while is the overall ionization constant. Which of the following statements are true?A. B. is a stronger acid than and C. D. Choose the correct answer from the options given below:
A
A and B only
B
A and C only
C
B, C and D only
D
A, B and C only

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