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The formation of the oxide ion, , from oxygen atom requires first an exothermic and then an endothermic step as shown below: Thus the process of formation of in gas phase is unfavourable though is isoelectronic with neon. It is due to the fact that:

  1. A
    Oxygen is more electronegative.
  2. B
    Addition of electron in oxygen results in larger size of the ion.
  3. C
    Electron repulsion outweighs the stability gained by achieving noble gas configuration.
  4. D
    ion has comparatively smaller size than oxygen atom.

Solution & Step-by-step Explanation

The first electron gain enthalpy of oxygen is negative (exothermic) because energy is released when an electron is added to a neutral atom. However, adding a second electron to the ion requires overcoming significant electrostatic repulsion between the already negative ion and the incoming electron. This energy requirement () is so high that it outweighs the stability gained by reaching the Neon-like noble gas configuration.

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The formation of the oxide ion, , from oxygen atom requires first an exothermic and then an endothermic step as shown below: Thus the process of formation of in gas phase is unfavourable though is isoelectronic with neon. It is due to the fact that:
A
Oxygen is more electronegative.
B
Addition of electron in oxygen results in larger size of the ion.
C
Electron repulsion outweighs the stability gained by achieving noble gas configuration.
D
ion has comparatively smaller size than oxygen atom.

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