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The variation of the boiling points of the hydrogen halides is in the order . What explains the higher boiling point of hydrogen fluoride?

  1. A
    The bond energy of molecules is greater than in other hydrogen halides.
  2. B
    The effect of nuclear shielding is much reduced in fluorine which polarizes the molecule.
  3. C
    The electronegativity of fluorine is much higher than for other elements in the group.
  4. D
    There is strong hydrogen bonding between molecules.

Solution & Step-by-step Explanation

Although boiling point generally increases with molecular mass due to Van der Waals forces (), has the highest boiling point because of the presence of strong intermolecular hydrogen bonding caused by the high electronegativity of fluorine.

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The variation of the boiling points of the hydrogen halides is in the order . What explains the higher boiling point of hydrogen fluoride?
A
The bond energy of molecules is greater than in other hydrogen halides.
B
The effect of nuclear shielding is much reduced in fluorine which polarizes the molecule.
C
The electronegativity of fluorine is much higher than for other elements in the group.
D
There is strong hydrogen bonding between molecules.

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