The wavelengths involved in the spectrum of deuterium () are slightly different from that of hydrogen spectrum, because:
- Asize of the two nuclei are different
- Bnuclear forces are different in the two cases
- Cmasses of the two nuclei are different
- Dattraction between the electron and the nucleus is different in the two cases
Solution & Step-by-step Explanation
The Rydberg constant depends on the reduced mass of the electron-nucleus system. Since the mass of the deuterium nucleus is approximately twice that of the hydrogen nucleus, their reduced masses differ slightly, leading to shifts in the spectral wavelengths.