Which of the following cubes in the answer figures cannot be made based on the unfolded cube in the question figure?

From the unfolded dice structure, we can identify the opposite faces because alternative faces are opposite to each other:
Face with Circle with dots is opposite to the Blank face.

Face with Cross (X) is opposite to the Five dots block.

Face with Shaded circle is opposite to the Four lines symbol.

A cube cannot be formed if two opposite faces are shown adjacent to each other. By verifying the option layouts against these opposite face restrictions, Option A shows faces that violate the rule.