Which of the following words will come second when arranged according to the English dictionary order?

Let's arrange the given words in alphabetical dictionary order. All words start with the prefix "St". We compare them character by character:
1. Station $\to \text{S-T-A-T-I}...$
2. Storage $\to \text{S-T-O}...$
3. Staying $\to \text{S-T-A-Y}...$
4. Stately $\to \text{S-T-A-T-E}...$

Comparing the third letter:

* Three words (Station, Staying, Stately) have 'A'.
* One word (Storage) has 'O'. Since 'A' comes before 'O', Storage comes last.

Now compare the words starting with "Sta":

* Station $\to$ fourth letter is 'T' (followed by 'I')
* Staying $\to$ fourth letter is 'Y'
* Stately $\to$ fourth letter is 'T' (followed by 'E')

Since 'T' comes before 'Y', Staying comes third. Now compare Station and Stately based on their fifth letters:

* Stately $\to$ fifth letter is 'E'
* Station $\to$ fifth letter is 'I'

Since 'E' comes before 'I', the sorted order is:

1. Stately
2. Station
3. Staying
4. Storage

The word that comes second in the English dictionary is Station.