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Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species ?

  1. A
    Cl < F < S < O
  2. B
    O < S < F < Cl
  3. C
    S < O < Cl < F
  4. D
    F < Cl < O < S

Solution & Step-by-step Explanation

Electron gain enthalpy is a measure of the energy change when an electron is added to an atom. The more negative the electron gain enthalpy, the more stable the anion formed. To determine the correct order, we need to consider the electron gain enthalpies of the given atomic species. Generally, the electron gain enthalpy becomes more negative as we move from left to right across a period in the periodic table, due to the increasing effective nuclear charge. However, there are exceptions, especially when considering the noble gases and the elements in the same group. Fluorine has a very negative electron gain enthalpy due to its high electronegativity and the stability of the F- ion. Chlorine also has a negative electron gain enthalpy but less so than fluorine. Oxygen has a less negative electron gain enthalpy than both fluorine and chlorine because the added electron goes into a higher energy level, and there is also a significant electron-electron repulsion in the small oxygen atom. Sulfur, being in the same group as oxygen but in a lower period, has an even less negative electron gain enthalpy due to its larger size and lower electronegativity. Therefore, the correct order from the most negative to the least negative electron gain enthalpy is F > Cl > O > S, which corresponds to option (B) when considering the absolute values and the negative sign. However, my analysis led to a comparison rather than selecting the exact option provided, indicating a need to directly compare the options given. The correct order with the negative sign considered should reflect the most negative (most stable) first, which would actually align with the general trend of electronegativity and atomic size considerations. Thus, the correct sequence reflecting the negative sign should start with the most negative value, which would be associated with the element that gains an electron most readily.

Practice this question

Try it yourself before checking the explanation above.

Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species ?
A
Cl < F < S < O
B
O < S < F < Cl
C
S < O < Cl < F
D
F < Cl < O < S

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