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GATE CY 2013 Question Paper (20-Jan-2013) (Shift 2)

Medium 64 Questions 180 min 100 marks

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Question No: 41Difficulty: mediumMarks: 2mcq
The major product(s) formed in the reaction sequence given below is(are)

image
Question No: 42Difficulty: mediumMarks: 2mcq
Match the compounds in the column I with the photochemical reactions that they can undergo given in the column II
III
(i) image(p) oxa-di- -methane rearrangement
(ii) image(q) Paterno-Buchi reaction
(iii)image(r) intramolecular [2+2]-cycloaddition
(s) photoenolisation
Question No: 43Difficulty: mediumMarks: 2mcq
is an eigen function of the operator . The corresponding eigen value is
Question No: 44Difficulty: mediumMarks: 2mcq
The infrared spectrum of HCl gas shows an absorption band centered at . The zero point energy of HCl molecule under harmonic oscillator approximation is
Question No: 45Difficulty: mediumMarks: 2mcq
For the reaction at 298 K,
given the values, and , is

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