GATE CY 2015 Question Paper (31-Jan-2015) (Shift 1)

The major product formed in the following reaction is

The tetrapeptide, Ala-Val-Phe-Met, on reaction with Sanger's reagent, followed by hydrolysis gives

The major product formed in the following reaction is

The Beckmann rearrangement of a bromoacetophenone oxime ($C_8{H}_{8}BrNO$) gives a major product having the following ${}^{1}HNMR(\delta ,ppm)$: $9.89(s,1H)$, $7.88(s,1H)$, $7.45(d,1H,J=7.2Hz)$, $7.17(m,1H)$, $7.12(d,1H,J=7.0Hz)$, $2.06(s,3H)$. The structure of the product is

The major products, K and L formed in the following reactions are