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GATE CY 2022 Question Paper (06-Feb-2022) (Shift 2)

Medium 65 Questions 180 min 100 marks

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Question No: 46Difficulty: mediumMarks: 2mcq
The CORRECT distribution of the products in the following reaction is

image
Question No: 47Difficulty: mediumMarks: 2mcq
The addition of K₄[Fe(CN)₆] to a neutral aqueous solution of the cationic species of a metal produces a brown precipitate that is insoluble in dilute acid. The cationic species is
Question No: 48Difficulty: mediumMarks: 2mcq
The electronic spectrum of a Ni(II) octahedral complex shows four d-d bands, labelled as P, Q, R, and S. Match the bands corresponding to the transitions.
**λ, nm(ε, M⁻¹ cm⁻¹)**Transitions
P1000 (50)I³A (F) → ³T (P)
Q770 (8)II³A2g(F) → ³T1g(F)
R630 (55)III³A2g(F) → ³T₂g(P)
S375 (110)IV³A2g(F) → ¹E (D)
Question No: 49Difficulty: mediumMarks: 2mcq
In the following table, the left column represents the rigid-rotor type and the right column shows a set of molecules.
AB
PSymmetric rotor (oblate)ISiH₄
QSymmetric rotor (prolate)IICH₃Cl
RSpherical rotorIIIC₆H₆
SAsymmetric rotorIVCH₃OH
VCO₂
The CORRECT match is
Question No: 50Difficulty: mediumMarks: 2mcq
The CORRECT statement regarding the following three normal modes of vibration of SO₃ is

image

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