Carbon, silicon and germanium have four valence electrons each. At room temperature which one of the following statements is most appropriate?
- AThe number of free conduction electrons is significant in C but small in Si and Ge.
- BThe number of free conduction electrons is negligibly small in all the three.
- CThe number of free electrons for conduction is significant in all the three.
- DThe number of free electrons for conduction is significant only in Si and Ge but small in C.
Solution & Step-by-step Explanation
Carbon (Diamond), Silicon, and Germanium all belong to the same group. However, their band gaps differ significantly:Carbon (Diamond) has a very large band gap , making it an insulator. The number of free electrons at room temperature is negligible.Silicon and Germanium have smaller band gaps, allowing some electrons to jump to the conduction band at room temperature.Therefore, Si and Ge have significant free electrons compared to C at room temperature.