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The following mechanism has been proposed for the reaction of with to form : If the second step is the rate determining step, the order of the reaction with respect to is:

  1. A
    1
  2. B
    0
  3. C
    3
  4. D
    2

Solution & Step-by-step Explanation

Rate depends on the slow step: .From the first fast equilibrium step:

Substitute this into the rate equation:

The order with respect to is .

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The following mechanism has been proposed for the reaction of with to form : If the second step is the rate determining step, the order of the reaction with respect to is:
A
1
B
0
C
3
D
2

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